Triphenylsilyl hydroperoxide
WebHydroperoxide,triphenylsilyl cas 2319-38-2 Cas No: 2319-38-2: No Data: No Data: No Data: Hangzhou Fandachem Co.,Ltd: Contact Supplier: 2319-38-2 Usage. 2319-38-2 SDS. SAFETY DATA SHEETS According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition. WebBis(triphenylsilyl) chromate [(Ph 3 SiO) 2] can be used as a catalyst:. For ethylene polymerization. For the conversion of secondary benzylic and allylic trimethylsilyl ethers to ketones by oxidation reaction using tert-butyl hydroperoxide.; It can also be used to prepare supported catalysts with silica gel or montmorillonite K-10.
Triphenylsilyl hydroperoxide
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WebAug 6, 2024 · hydroperoxides) are peroxide compounds of the general formula ROOM, where R is an alkyl, aryl, or acyl radical, and M is a metal of Periodic Group 1.1 Organic peroxides … WebNov 9, 2004 · Triphenylsilyl hydroperoxide is degraded by equimolar quantities of NaN [Si (CH3)3]2, NaH, NaNH2 or Li-n-C4H9 in aprotic solvents ( −80 to −20°C) via a stable blue radical anion to phenol and [...
WebGHS Hazard and Precautionary Statements. Hazard Statements: H315-H319-H335 Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Triphenylsilyl hydroperoxide C18H16O2Si CID 286902 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.
WebThe reaction of triphenylsilyl halides with sodium naphthalenide yields mainly hexaphenyldisilane, a small amount of 1,4-bistriphenylsilyl-1,4-dihydronaphthalene, and … WebBis (triphenylsilyl) chromate 96% Synonym (s): Bis (triphenylsilyl) ester chromic acid Linear Formula: [ (C6H5)3SiO]2CrO2 CAS Number: 1624-02-8 Molecular Weight: 634.79 EC …
WebBis (triphenylsilyl) Chromate is an organometallic silyl chromate catalyst for polymerization and benzylic oxidation reactions. Organometallics are useful reagent, catalyst, and precursor materials with applications in thin film deposition, industrial chemistry, pharmaceuticals, LED manufacturing, and others.
WebMar 10, 1992 · Read "ChemInform Abstract: Bis(triphenylsilyl) Chromate‐Catalyzed Oxidation of Silyl Ethers by tert‐Butyl Hydroperoxide., ChemInform" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. brian in love family guyWebJan 1, 1979 · Triphenylsilyl hydroperoxide behaves similarly to peracids toward olefins, ketones and allylic alcohols. The altered reactivity observed with many reagents when in … court 141 livingston streetWebJul 24, 2024 · Preparative Methods: prepared by treatment of triphenylsilyl fluoride with tetrabutylammonium fluoride (TBAF), 1 or by reaction of triphenylsilane with tetrabutylammonium hydrogen difluoride. 2; Purification: recrystallized from EtOAc or CH 2 Cl 2 /hexanes. Handling, Storage, and Precautions: reagent is extremely sensitive to acid. courtaction.co.krWebAldrich-360058; (Triphenylsilyl)acetylene 0.98; CAS Number: 6229-00-1; Linear Formula: (C6H5)3SiC///CH; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. court administration fergus falls mnWebDec 15, 2006 · Hydrogen peroxide or tert butyl hydroperoxide in contact with basic alumina will epoxidize olefins. Triphenylsilyl hydroperoxide behaves similarly to peracids toward olefins, ketones and allylic ... court administration sherburne countyWeb23.3 bis(Trimethylsilyl)peroxide and t-Butyl Trimethylsilyl Peroxide (23.2) bis(Trimethylsilyl)peroxide might be considered to be analogous to hydrogen peroxide. It … brian in loveWebBritish Journal of Applied Physics. year of publication , 16 (3), pg no. Reaction with CrO 3leads readily to bis(triphenylsilyl) chromate which acts as a catalyst in the oxidation of … court administration hibbing mn